顶空气相色谱法测定地层水中的苯系物

利用极性聚乙二醇弹性石英毛细管柱分离苯系物，在线顶空气相色谱法测定地层水中的苯系物。讨论了色谱柱、载气压力、液相体积、顶空压力、顶空加热温度等因素对测定的影响。该方法实现了地层水中苯、甲苯、乙苯、对二甲苯、间二甲苯、邻二甲苯、异丙苯、苯乙烯等各组分的完全分离，方法的检出限在0．07—0．23μg／L，8次测定相对标准偏差在2．98％-4．91％，加标回收率为95．2％-104％。方法可用于地层水等液体样品中苯系物的测定。     

基于光谱信息的遥感图像空间域自适应滤波

遥感图像往往由于内外因素的干扰含有各种噪声 ,为提高图像质量人们对其进行滤波。常规的滤波方式完全基于图像空间域 ,在消除异常点使图像平滑的同时使边界变得不清楚从而使图像模糊 ;或者正相反 ,在边缘信息得到增强时也放大了图像噪声而使图像变得粗糙。该文的自适应滤波方法充分利用多光谱和高光谱遥感图像的光谱维信息 ,滤波时不仅要使均匀的地块得到平滑 ,而且要使地块间的边缘、局部的异常点、线仍然得到保存、在光滑的同时尽量保持原有的数值特征     

高光谱数据在数据库中的高效存储技术研究

通过分析高光谱数据的特点 ,结合数据库系统开发实践 ,提出了高光谱数据集 ,包括图像、光谱、属性等 ,在关系数据库中的存储规范。结合ORACLE数据平台 ,提出了 3种高光谱数据的存储模式 ,并结合应用实例进行对比 ,分析了各自的优缺点以及适用条件。     

应用高光谱遥感数据估算土壤表层水分的研究

土壤水分是土壤的重要组成部分，它在陆地表层和大气之间的物质和能量交换方面扮演着重要角色，寻求快速而准确的方法估算土壤水分具有重要意义。通常，从可见光一近红外对土壤表层水分的估计多是建立在土壤水分与反射率的关系之上的。而在土壤水分含量不高时，土壤水分的增加使土壤光谱反射率在整个波长范围内降低，尤其在760nm，970nm，1190nm，1450nm，1940nm和2950nm等水分吸收波段，而在土壤水分含量较高时，土壤水分的增加会使土壤光谱反射率在某些光谱波段升高。而土壤水分的估计往往是基于土壤水分与土壤水分吸收波段的吸收强度之间的线性关系上，虽然这些经验的方法对于估算某些土壤的表层水分含量是有效的，但这些关系应用于其它条件(如不同种类土壤、土壤湿度变化范围很大的情况)时却面临很多困难，这与土壤的光谱反射率是由土壤的组成成分(土壤水分、有机质、氧化铁和粘土矿物等)的含量和它们在土壤中的分布密切相关。微分技术处理“连续”的光谱是遥感中常用的数学方法，微分技术能部分消除低频光谱成分的影响。现在微分光谱已广泛地应用于研究植被的生物物理参数、矿物和有机质等。然而利用微分光谱对土壤水分反演的研究却鲜见报道。本文通过对实验室中多种不同类型的土壤进行光谱与土壤表层水分含量进行观测，探讨了通过土壤反射率与微分光谱对土壤表层水分的反演方法。4种类型的土壤光谱数据(反射率(R)，反射率倒数的对数(log(1／R))，反射率的一阶微分光谱(dR／dλ)，反射率倒数的对数的一阶微分光谱(d(log(1／R))／dλ))与土壤表层水分之间的关系在本文中得到分析，R与log(1／R)对于不同土壤类型与土壤表层水分都很敏感，说明通过R与log(1／R)反演土壤表层水分受土壤类型的影响很大，而dR／dλ，d(log(1／R))／dλ)对土壤类型却不敏感，对土壤表层水分较为敏感，说明dR／dλ和d(log(1／R))／dλ)对于反演不同类型土壤具有很大的潜力，微分光谱与土壤水分在某些波段具有显著的相关性。通过随机对9种土壤(各具有4个土壤水分)的数据建立反演土壤水分的模型，并其他9种土壤(各具有4个土壤水分)的数据进行验证模型，结果表明，dR／dλ和d(log(1／R))／dλ)能够显著提高R与log(1／R)对于不同土壤类型土壤表层水分的反演精度，由于吸收过程是非线性的，在四种类型的土壤光谱数据中，总体来说，d(log(1／R))／dλ)具有最好的能力预测不同类型土壤的表层水分含量。     

四川盆地潜在震源区的细致划分

四川盆地包括川中台拱和川东陷褶束的范围，具有相对稳定的大地构造环境.鉴于该地区地震活动水平相对较低、发震构造不甚明确的特点，在编制1990年版中国地震烈度区划图时，划分的潜在震源区面积也相对较大.本文在总结四川盆地中强地震（Ms=4.7-5.7）发震构造条件的基础上，用地震构造类比原则对四川盆地的潜在震源区进行了重新划分.确定潜在震源区边界时，充分考虑了背斜轴走向、背斜构造的影响带宽度、小震活动密集条带和余震的分布范围.得到了四川盆地更加细致的潜在震源区划分方案.这对于低地震活动水平地区的潜在震源区的细化研究具有一定参考意义。     

西藏松西地区辉绿玢岩岩石化学、地球化学特征及构造环境

青藏高原南羌塘石炭纪-二叠世地层中侵入大量的辉绿玢岩岩墙群，其侵位时代为晚古生代。区域资料显示，这一时期该地区处于冈瓦纳大陆北部边缘。岩石化学、地球化学特征表明，辉绿玢岩与洋脊型、洋岛型及典型的大陆裂谷玄武岩都有明显区别，显示出大陆拉张带（或初始裂谷）的拉斑玄武岩特征。辉绿玢岩是冈瓦纳被动陆缘在晚古生代裂解的产物。     

Spatial character of the gaseous and particulate state compound correlation of urban atmospheric pollution in winter and summer

The spatial/temporal variation information of atmospheric dynamic-chemical processes at observation site points of the "canopy" boundary of Beijing urban building ensemble and over urban area "surface", as well as the seasonal correlation structure of the gaseous and particulate states of urban atmospheric pollution (UAP) and its seasonal conversion feature at observation points are investigated, using the comprehensive observation data of the Beijing City Air Pollution Observation Experiment (BECAPEX) in winter and summer 2003 with a "point-surface" combined research approach. By using "one dimension spatial empirical orthogonal function (EOF)" principal component analysis (PCA) mode, the seasonal change of gaseous and particulate states of atmospheric aerosols and the association feature of pollutant species under the background of the complicated structure of urban boundary layer (UBL) are analyzed. The comprehensive analyses of the principal components of particle concentrations,gaseous pollutant species, and meteorological conditions reveal the seasonal changes of the complex constituent and structure features of the gaseous and particulate states of UAP to further trace the impact feature of urban aerosol pollution surface sources and the seasonal difference of the component structure of UAP. Research results suggest that in the temporal evolution of the gaseous and particulate states of winter/summer UAP, NOx, CO, and SO2 showed an "in-phase" evolution feature, however, O3 showed an "inverse-phase" relation with other species,all possessing distinctive dependent feature. On the whole, summer concentrations of gaseous pollutants CO, SO2, and NOx were obviously lower than winter ones, especially, the reduction in CO concentration was most distinctive, and ones in SO2 and NOx were next. However, the summer O3 concentration was more than twice winter one. Winter/summer differences in PM10and PM2.5 particle concentrations were relatively not obvious, which indicates that responses of PM10 and PM2.5 particle concentrations to the difference of winter/summer heating period emission sources are far less distinctive than those of NOx, SO2, and CO. The correlation feature of winter/summer gaseous and particulate states depicts that both PM10 and PM2.5 particles were significantly correlated with NOx, and their correlations with NOx are more significant than those with other pollutants. Through PCA, it is found that there was a distinctive difference in the principal component combination structure of winter/summer PM10 and PM2.5 particles: SO2 and NOx dominated in the principal component of winter PM10 and PM2.5 particles; while CO and NOx played the major role in the principal component of summer PM10 and PM2.5 particles. For winter/summer PM10 and PM2.5 particles, there might exist the gaseous and particulate states correlation structures of different "combinations" of such dependent pollutant species. Research results also uncover that the interaction processes of gaseous and particulate states were also related with the vertical structure of UBL, that is to say, the low value layer of UBL O3 concentration was associated with the collocation of atmospheric vertical structures of the low level inversion,inverse humidity, and small wind, which depicts summer boundary layer atmospheric character, i.e.the compound impact of the dependent factor "combination" of wind, temperature, and humidity elements and their collocation structure on the variations of different gaseous pollutant concentrations. Such a depth structure of the extremely low value of O3 concentration in the UBL accords with its "inverse-phase" relation with other gaseous pollutant species. The PCA of meteorological factors associated with PM10 and PM2.5 concentrations also reveals the sensitivity of PM10 and PM2.5 concentration to the combinatory feature of local meteorological conditions.     

城市建成环境对居民体力活动的影响 ——以福州市的经验研究为例

利用福州中心城区的社会调查、POI、道路网、用地性质等数据,在社区尺度探究城市建成环境对居民休闲型中高强度体力活动的影响。研究发现：① 低密度土地利用与体力活动时长呈正向关联,功能单一和邻近主干道则对体力活动起到抑制作用。② 体力活动目的地对不同人群具有差异化影响,体育用地和付费运动场所仅能促进中高阶层和中高收入者的体力活动,而周边公共运动设施的丰富程度更具普适性意义。③ 通过纳入运动偏好和单独分析保障房、单位大院及房改房住户达到规避居住自选择的目的,证明上述建成环境特征对体力活动的影响是独立且稳健的。     

南海东北部内潮的模态结构和传播

The evolution of energy, energy flux and modal structure of the internal tides(ITs) in the northeastern South China Sea is examined using the measurements at two moorings along a cross-slope section from the deep continental slope to the shallow continental shelf. The energy of both diurnal and semidiurnal ITs clearly shows a～14-day spring-neap cycle, but their phases lag that of barotropic tides, indicating that ITs are not generated on the continental slope. Observations of internal tidal energy flux suggest that they may be generated at the Luzon Strait and propagate west-northwest to the continental slope in the northwestern SCS. Because the continental slope is critical-supercritical with respect to diurnal ITs, about 4.6 kJ/m~2 of the incident energy and 8.7 kW/m of energy flux of diurnal ITs are reduced from the continental slope to the continental shelf. In contrast, the semidiurnal internal tides enter the shelf because of the sub-critical topography with respect to semidiurnal ITs.From the continental slope to the shelf, the vertical structure of diurnal ITs shows significant variation, with dominant Mode 1 on the deep slope and dominant higher modes on the shelf. On the contrary, the vertical structure of the semidiurnal ITs is stable, with dominant Mode 1.     

徕卡RTC360三维激光扫描仪在竣工测量中的应用

徕卡RTC360不仅操作简单、扫描速度快，而且非常智能。可以实时跟踪计算两个连续站点间的相对位置，点云实时预拼接。后期搭配Register360智能拼接软件，点云智能拼接处理，无需人工干预，简单高效。